Permian volcanic rocks from the Apuseni Mountains (Romania): Geochemistry and tectonic constraints     

Ionel Nicolae  Ioan Seghedi  Iuliu Boboş  Maria do Rosário Azevedo  Sara Ribeiro  Mihai Tatu 《Chemie der Erde / Geochemistry》2014

An Early Permian volcanic assemblage is well exposed in the central-western part of the Apuseni Mountains (Romania). The rocks are represented by rhyolites, basalts and subordinate andesites suggesting a bimodal volcanic activity that is intimately associated with a post-orogenic (Variscan) syn-sedimentary intra-basinal continental molasse sequences. The mafic and mafic-intermediate rocks belong to sub-alkaline tholeiitic series were separated in three groups (I–III) showing a high Th and Pb abundances, depletion in Nb, Ta and Sr, and slightly enriched in LREE patterns (La_N/Yb_N = 1.4–4.4). Isotopically, the rocks of Group I have the initial ratios ⁸⁷Sr/⁸⁶Sr_(i) = 0.709351–0.707112, ¹⁴³Nd/¹⁴⁴Nd_(i) = 0.512490–0.512588 and high positive ?_Nd270 values from 3.9 to 5.80; the rocks of Group II present for the initial ratios values ⁸⁷Sr/⁸⁶Sr_(i) = 0.709434–0.710092, ¹⁴³Nd/¹⁴⁴Nd_(i) = 0.512231–0.512210 and for ?_Nd270 the negative values from −1.17 to −1.56; the rocks of Group III display for the initial ratios the values ⁸⁷Sr/⁸⁶Sr_(i) = 0.710751–0.709448, ¹⁴³Nd/¹⁴⁴Nd_(i) = 0.512347–0.512411 and for ?_Nd270 the positive values from 1.64 to 2.35. The rocks resembling continental tholeiites, suggest a mantle origin and were further affected by fractionation and crustal contamination. In addition, the REE geochemistry (1 > Sm_N/Yb_N < 2.5; 0.9 > La_N/Sm_N < 2.5) suggests that these rocks were generated by high percentage partial melting of a metasomatized mantle in the garnet peridotite facies. The felsic rocks are enriched in Cs, Rb Th and U and depleted in Nb, Ta, Sr, Eu, and Ti. The REE fractionation patterns show a strong negative Eu anomaly (Eu/Eu* = 0.23–0.40). The felsic rocks show the initial ratios the values: ⁸⁷Sr/⁸⁶Sr_(i) = 0.704096–0.707805, ¹⁴³Nd/¹⁴⁴Nd_(i) = 0.512012–0.512021 and for ?_Nd270 the negative values from −5.27 to −5.44. They suggest to be generated within the lower crust during the emplacement of mantle-derived magmas that provided necessary heat to crustal partial melting.  相似文献   

熔融制样波长色散X射线荧光光谱法测定白云石中钙镁硅铁铝   总被引：4，自引：3，他引：1  

褚宁  李卫刚  蒋晓光  张彦甫  毕孝瑞 《岩矿测试》2014,33(6):834-838

白云石属碳酸盐矿物,应用熔融制样X射线荧光光谱法测定其中主次量组分钙、镁、硅、铁、铝时,由于白云石灼烧减量大,在试料片制备过程中,如果以干基试料制备试料片,除灼烧减量外还有少量其他组分被分解出的大量CO₂带走,导致试料损失,测定结果偏低;如果以灼烧基试料制备试料片,由于灼烧后的试料极易吸收空气中的水分和CO₂,同样使测定结果偏低。基于质量守恒原理,本文直接以灼烧减量测量后的灼烧基试料质量作为试料量(即灼烧减量测定所称量的干基试料量扣除灼烧减量的量),以四硼酸锂为熔剂,5%碘化铵溶液为脱模剂,试料与熔剂的稀释比为1:10,于1050℃熔融15 min以上制备的试料片透彻、玻璃化程度高。以白云石标准物质和标准样品作为标准试料,制作各组分的标准曲线的相关系数在0.9940~0.9994之间;方法检出限为0.011%~0.48%;标准物质和标准样品的测定值与认定值基本一致,各组分的相对标准偏差(RSD,n=11)在0.5%~1.7%之间,方法具有较好的重现性。本方法以1050℃灼烧后的试样作为试料制备XRF分析样片,最大限度地降低了灼烧减量因素(空气中的水分和CO₂)对测定结果的影响,适用于白云石及其煅烧物中钙、镁、硅、铁、铝等组分的同时测定。  相似文献   

Discrete modeling of strain accumulation in granular soils under low amplitude cyclic loading     

《Computers and Geotechnics》2014

An advanced understanding of the strain accumulation phenomenon in granular soils subjected to low amplitude cyclic loading with relatively high frequency is needed to enhance the ability to predict the settlement of granular soils induced by vibrations. In the current study, the discrete element method is used to study this phenomenon. A loose and a medium dense sample composed of a relatively large number of spheres are considered. A series of stress controlled cyclic triaxial tests with different excitation amplitudes and frequencies is performed on these samples at different static stress states. The response of these samples at the macroscopic and microscopic scales is analyzed. The sample density, the cyclic stress amplitude and the static stress state importantly affect strain accumulation. However, the cyclic excitation frequency has a small effect on strain accumulation. At the microscopic scale, frictional sliding occurring at a few contacts continuously dissipates energy and the fraction of these contacts varies periodically during cyclic loading. The coordination number of these samples increases slightly as strain accumulates. However, the anisotropy remains almost constant during low amplitude cyclic excitation. A qualitatively good agreement between numerical and experimental results is found.  相似文献   

淮南煤田潘三煤矿4-2煤中矿物对岩浆侵入的响应     

李秀芝  ;陈健  ;康彧  ;刘桂建 《中国煤炭地质》2014,(7):12-14

以淮南煤田潘三煤矿4-2煤层中的岩浆岩、天然焦和煤样品为研究对象,利用X射线衍射仪和X射线荧光光谱仪测试其矿物组成和主量元素含量,研究地下岩浆侵入对煤中矿物成分的影响。结果表明:煤变质成天然焦后,其总的矿物含量增多,并伴随着后生矿物如微斜长石和镁绿泥石的出现。天然焦中后生矿物的组成元素可能来源于岩浆或热液中的主量元素如Si、Al、Na、K、Fe和Mg。  相似文献   

贵州盘县土城向斜南西翼二叠系龙潭组地球化学特征及意义     

田利  谢红东  张学东 《中国煤炭地质》2014,(7):15-20

为探讨盘县土城向斜龙潭组物源及沉积环境,对ZK402号孔龙潭组样品进行微量元素及稀土元素测试分析,结果显示:龙潭期的水体为微咸水—半咸水的淡水环境,水体分层不强的厌氧环境—水体分层及底层水体呈现H2S的厌氧环境;泥岩中稀土含量高,源岩主要为钙质泥岩和碱性玄武岩。根据砂岩粒度分析、薄片鉴定、电子探针等综合分析,在龙潭组中识别出三角洲和障壁砂坝—潟湖沉积相以及三角洲前缘、下三角洲平原、上三角洲平原、潮坪、潟湖等亚相,龙潭早、晚期以潟湖相为主,龙潭中期以分流河道和分流间湾广泛发育为特征。  相似文献   

聚合物钻井液在河北广宗勘探区深孔施工中的应用     

孙贵生 《中国煤炭地质》2014,(6):71-73

在河北广宗勘探区深孔施工中,由于地表钻探用水水质影响及原钻井液体系不合适,造成钻井液性能指标达不到要求,性能难以控制,尤其失水量严重超标,接连发生孔内事故。针对存在的问题,经过分析和实验,采用化学方法处理钻探用水,选用聚合物钻井液,解决了深部钻孔施工存在的难点,收到了较好的效果,单孔深度达到1937.35m,并刷新了本单位及局属单位的钻探记录。  相似文献   

山西吕梁山北段中生代构造特征及对成矿的制约          下载免费PDF全文

孙思磊  张兆琪 《中国地质调查》2014,6(3):56-62

为进一步研究山西吕梁山北段中生代构造特征及对成矿的制约,利用数字化填图方法,在偏关县一带开展1:25万区域地质调查。发现几条中生代大型构造带,查明了这些大型构造带的空间展布、性质、断裂组合及运动学特征; 证实了中生代为该区重要的多金属成矿期,成矿作用尽管与中生代岩浆活动关系密切,但在空间上分布受NE向隐伏构造的制约; 大型挠褶构造是地壳强烈隆升的标志,区内大型构造带多数是在挠褶构造的基础上叠加断层而形成的。该研究对于探讨山西中—新生代构造的演化发展具有重要意义。  相似文献   

G359.95-0.04: an energetic pulsar candidate near Sgr A*     

Q. D. Wang  F. J. Lu  E. V. Gotthelf 《Monthly notices of the Royal Astronomical Society》2006,367(3):937-944

We report the discovery of a prominent non-thermal X-ray feature located near the Galactic centre that we identify as an energetic pulsar wind nebula. This feature, G359.95-0.04, lies 1-lyr north of Sgr A* (in projection), is comet like in shape, and has a power-law spectrum that steepens with increasing distance from the putative pulsar. The distinct spectral and spatial X-ray characteristics of the feature are similar to those belonging to the rare class of ram-pressure confined pulsar wind nebulae. The luminosity of the nebula at the distance of Sgr A*, consistent with the inferred X-ray absorptions, is   L_x ∼ 1 × 10³⁴ erg s⁻¹  in the 2–10 keV energy band. The cometary tail extends back to a region centred at the massive stellar complex IRS 13 and surrounded by an enhanced diffuse X-ray emission, which may represent an associated supernova remnant. Furthermore, the inverse Compton scattering of the strong ambient radiation by the nebula consistently explains the observed TeV emission from the Galactic centre. We also briefly discuss plausible connections of G359.95-0.04 to other high-energy sources in the region, such as the young stellar complexes IRS 13 and SNR Sgr A East.  相似文献   

Composition of jovian dust stream particles     

Frank Postberg  Sascha Kempf  Simon F. Green  Neil McBride 《Icarus》2006,183(1):122-134

The Cassini spacecraft encountered Jupiter in late 2000. Within more than 1 AU of the gas giant the Cosmic Dust Analyser onboard the spacecraft recorded the first ever mass spectra of jovian stream particles. To determine the chemical composition of particles, a comprehensive statistical analysis of the dataset was performed. Our results imply that the vast majority (>95%) of the observed stream particles originate from the volcanic active jovian satellite Io from where they are sprinkled out far into the Solar System. Sodium chloride (NaCl) was identified as the major particle constituent, accompanied by sulphurous as well as potassium bearing components. This is in contrast to observations of gas in the ionian atmosphere, its co-rotating plasma torus, and the neutral cloud, where sulphur species are dominant while alkali and chlorine species are only minor components. Io has the largest active volcanoes of the Solar System with plumes reaching heights of more than 400 km above the moons surface. Our in situ measurements indicate that alkaline salt condensation of volcanic gases inside those plumes could be the dominant formation process for particles reaching the ionian exosphere.  相似文献   

A new interpretation of the remarkable X-ray spectrum of the symbiotic star CH Cyg     

Peter J. Wheatley  Timothy R. Kallman 《Monthly notices of the Royal Astronomical Society》2006,372(4):1602-1606

We have re-analysed the ASCA X-ray spectrum of the bright symbiotic star CH Cyg, which exhibits apparently distinct hard and soft X-ray components. Our analysis demonstrates that the soft X-ray emission can be interpreted as scattering of the hard X-ray component in a photoionized medium surrounding the white dwarf. This is in contrast to previous analyses in which the soft X-ray emission was fitted separately and assumed to arise independently of the hard X-ray component. We note the striking similarity between the X-ray spectra of CH Cyg and Seyfert 2 galaxies, which are also believed to exhibit scattering in a photoionized medium.  相似文献